Polymethyl methacrylate is synthesized by radical polymerization of
methyl methacrylate.
CH3 CH3
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x CH2=C → -(-CH2-C-)-x
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CO2CH3 CO2CH3
This type of polymerizatio reaction is usually started by a catalyst,
or an initiator such as oxygen, or a peroxide (an initiator of
free radicals). The polymerization mechanism is similar to that of
polystyrene from styrene, and polyvinyl chloride (PVC) from
vinyl chloride. The reaction can be continued until a desired
(average) chain length of the polymer is achieved. At this point, the
polymerization is stopped by addition of a free radical inhibitor.