The age at which a woman isn't expected to ever marry, might start lying about her age, or isn't considered attractive anymore. What, exactly this age is varies greatly.

"She was twenty-five and looked it, and so there was no longer any need for her to try to be attractive." (Gone With The Wind, describing India Wilkes).

(Note: the author of this write-up is 26 and doesn't consider herself an old maid.)