Since the 1913 edition of Webster's dictionary, the nomenclature of hydrocarbons has become more specific in regards to structure. Octane is now specifically a string of eight linked carbon atoms, like so:

  H H H H H H H H
  | | | | | | | |
H-C-C-C-C-C-C-C-C-H
  | | | | | | | |
  H H H H H H H H
Other forms of C8H18 are not considered octane, but are identified by naming the longest string of carbon atoms, then referencing the branches off of them, as in 2-methyl-heptane, below:
  H H H H H H H
  | | | | | | |
H-C-C-C-C-C-C-C-H
  | | | | | | |
  H | H H H H H
  H-C-H
    |
    H