Prior to the 20th century, the distance to the Sun was obtained using the Moon's distance, and some clever trigonometry:

Measure the angle between the Moon and the Sun when the Moon is exactly in its first quarter phase. This angle will be almost, but not quite 90.0 degrees. The Sun-Moon-Earth angle is exactly 90 degrees, so the Sun, Moon and Earth form a very skinny right triangle at the instant of the Moon's first (or third) quarter phase. We know two of the triangle's interior angles (90 degrees, and not quite 90 degrees), and the length of the enclosed side (384,400 km), so we can use trigonometry to determine the distance between the Earth and Sun.

Of course, now that we have RADAR, we don't have to be so clever.

Average distance to the Sun (a.k.a. one Astronomical Unit): 150 Million km.