Cp for short, this pentagonal molecule is useful and interesting because it is
aromatic when charged. That is, the Cp
- (cyclopentadienyl)
ion is symmetric (it is C
5H
5 and flat) so it can readily form
metal-pi interactions. One of the first zero valent metal complexes (zinc, i thinc) was with two Cp ions sanwiching the metal between them. It has since become much used to complex metals or as a production route for
cyclophanes or other exotic structures.