This is Everything2's science writing group, existing to encourage, facilitate and organise the writing and discussion of science on this site. Members are usually willing to give feedback on any writing on scientific topics, answer questions and correct mistakes.

The E2_Science joint user is here make it easier to collectively edit and maintain the various indexes of science topics: Scientists and all its sub-indexes, physics, astronomy, biochemistry and protein. More may follow. It also collects various useful links on its home node.

Note that there is also a separate e^2 usergroup for the discussion of specifically mathematical topics.

How about logging in?


E2science Writeups

pH is the standard measure of the acidity or alkalinity of a solution1. It relates to the concentration of free protons in a solution – a large number of protons corresponds to a low pH, which is to say an acidic solution. If a particularly small number of protons is available, the pH is high and the solution is alkaline.

If that sounds a bit abstract, bear in mind that it's just a physical description of a very familiar chemical property – acidity is what makes things taste sour; some languages, like German, have the same word for 'sour' and 'acidic'. It's also one of the first things anyone ever learns about chemistry, so it's interesting that it's so difficult to pin down a clear physical description of the nature of pH – what do any of the well-known properties of acids have to do with protons?

How Acids Work

Besides tasting sour, acids also have the power to 'burn' or dissolve some materials. They do this with a kind of two-pronged attack. Every molecule of a standard acid is made of at least one hydrogen atom attached to one or more other atoms; the hydrogen breaks off from the rest of the molecule when it dissolves in water, leaving its sole electron behind2. Without its electron, a hydrogen atom is just a proton3. A proton has a positive charge, while the other part of the acid4 will have a negative charge – hydrochloric acid, for example, divides into positive hydrogen ions and negative chlorine ions.

Usually, anything with an excess charge like this will take any opportunity to lose it, and if a couple of those protons manage to grab a pair of electrons from somewhere they'll immediately make off with them to form a nice stable hydrogen molecule. Similarly, the negative ions will off-load their extra electrons at the first chance they get. One way to do this is by finding a positive ion to form a compound with; metals are handy for this, because they are essentially made of positive ions held together by free electrons. So the negative part of the acid (the anion) takes a positively charged atom out of the metal at the same time as the positive part (the proton, a cation) grabs an electron to maintain the overall charge. The metal dissolves into the liquid, and hydrogen bubbles escape.

How Bases Work

The flip-side of this is basicity (or alkalinity - an alkali is a base that dissolves in water). Bases remove protons, usually by giving them a hydroxide ion to react with5. Oxygen is very attractive to electrons6, so when hydroxide breaks away from a larger molecule, it takes an extra electron with it and leaves the remainder of the base with a positive charge. Often what's left behind is something that wasn't particularly keen on keeping that electron in the first place – the alkali metals can hardly shed them fast enough7, which is why they react so dramatically with water.

Since acids are proton donors, while bases are proton acceptors, they neutralise each other, producing water (OH- add H+ gives H2O) and a salt. Table salt (sodium chloride) is the salt you get from reacting hydrochloric acid with sodium hydroxide, but chemists define a salt as any compound that can be produced in this way.

Alkalis can also burn or dissolve various things, but the really interesting thing they do is to turn fats and oils into soaps. This process, known to humans for thousands of years, is called saponification, and it's the reason alkali solutions feel slippery on our fingers – our natural skin oils are changed instantly into detergents. The hydroxide breaks up the fat molecule into glycerol and fatty acids, while the other bit, for example the sodium or potassium, reacts with the fatty acid to produce soap.

Notes

1Note that acidity of a substance can also be measured by its dissociation constant, Ka. This describes a chemical, rather than its solution, so unlike pH it doesn't change with the strength of the solution, and doesn't necessarily apply to solutions at all
2Technically, I'm only talking about acids by the Arrhenius or Brønsted-Lowry definitions here; according to the Lewis definition an acid is a substance that can accept a pair of electrons to form a covalent bond
3Actually, a lone proton is so reactive that it will invariably attach itself to one or more nearby water molecules, making H3O (hydronium) or more likely something like H5O2 or H9O4
4Which, confusingly enough, now counts as an alkaline – the conjugate base of the acid
5The early Arrhenius theory of acidity only recognised compounds with hydroxide as alkalis, but this has now been superseded by the Brønsted-Lowry theory, in which any proton acceptor is a base, and any soluble base is an alkali
6That is, it is highly electronegative
7That is, they have very low electronegativity

Contact resistance is a hindrance to the flow of thermal, electrical, or kinetic energy at an interface between conductive materials. Such surfaces of contact can be formed by welding, soldering or simple mechanical contact.

Contact resistance is very important in the design, construction, testing and operation of electrical systems and thermal systems, because it causes energy loss and inefficiency in device operation and inaccuracy and unreliability in measurement.

Contact resistance can occur at the interface between different phases of the same material, where two pieces of the same material touch, or where two pieces of dissimilar materials touch. The resistance depends on many factors, including the actual surface area of contact (constriction resistance), the presence of oxides or other products of chemical reaction, absorption or adsorption, the cleanliness and the flatness of the two contact surfaces, differences in the conductivity of the materials, and tunneling resistance in thin-films.

One practical example of the important role of contact resistance in the operation of electrical circuits is in the operation of circuit breakers. A circuit breaker is like a switch that physically interrupts the flow of current in a circuit, usually to protect equipment and wiring systems against overcurrent. The ignition system of some internal combustion engines have contact breaker points that open and close rapidly in synchronization with the rotating engine crankshaft to deliver current with the right timing to a spark plug. The points can become fouled by oil or dirt, which acts as an insulator between the points and increases the contact resistance. The surface of the points can also be roughened by metal transfer from one surface to the other as a result of current arcing. Arcing may also cause formation of oxide layers on the point surfaces. Changes in the contact resistance of the points over time can cause mistiming of the ignition in the combustion chamber and poor engine performance. This is one reason that breaker-point ignitions have largely been replaced by electronic ignition systems in automobiles.

The interneurons constitute one of the three basic classes of neurons. They receive input only from neurons, either sensory neurons or other interneurons, and they output only to other neurons, which may be other interneurons, sensory neurons, or motor neurons. That distinguishes them from sensory (afferent) neurons, which have sensor cells as input, and motor (efferent) neurons, which output to muscle, glands or other tissues that produce some effect within the body or in the environment.

Interneurons make up all of the brain and most of the spinal cord, and number close to a hundred billion by some estimates. They are not all identical. The interneurons that make up the brain's cerebral cortex alone include pyramidal, spiny stellate, chandelier,and basket neurons, and perhaps hundreds of other kinds. (100 billion is like how many stars there are in the Milky Way or something.) It is the fantastically complex network of interneurons and their specialization into morphologically distinct areas within the brain and other parts of the central nervous system, such as the cerebrum, the thalamus, the cerebellum, the brainstem and various nerve plexuses around the body that allow for truly complex and intelligent behavior. Even the simplest of neural behavior, the reflex arc, involves at least one interneuron that connects an afferent neuron to an efferent neuron. Our knee-jerk reflex, more formally known as the patellar reflex, is an example of a reflex arc in which a single interneuron in the spinal cord links a sensory neuron to a motor neuron.


Venerable members of this group:

Oolong@+, CapnTrippy, enth, Professor Pi, RainDropUp, Razhumikin, Anark, The Alchemist, tom f, charlie_b, ariels, esapersona, Siobhan, Tiefling, rdude, liveforever, Catchpole, Blush Response, Serjeant's Muse, pimephalis, Hexter, BaronWR, abiessu, melknia, IWhoSawTheFace, 10998521, sloebertje, getha, siren, pjd, dgrnx, flyingroc, althorrat, elem_125, DoctorX, RPGeek, redbaker, unperson, Iguanaonastick, Taliesin's Muse, Zarkonnen, SharQ, Calast, idan, heppigirl, The Lush, ncc05, Lifix, Kurin, Akchizar, Palpz, Two Sheds, Gorgonzola, SciPhi, SyntaxVorlon, Redalien, Berek, fallensparks, GunpowderGreen, dichotomyboi, sehrgut, cordyceps, maverickmath, eien_meru, museman, cpt_ahab, mcd, Pandeism Fish, corvus, decoy hunches, StuartO)))$+, raincomplex, Glowing Fish, Tem42@
This group of 74 members is led by Oolong@+