The classification system is fundamentally biased towards the mores of the period in which it was created, notice for example that Christianity has 5 times the space of Judaism, despite Judaism having an older and (arguably) richer history.
Notice also that many things are Sciences but that Science is distinct in some unspecified way.
The Library of Congress website explaining the Library of Congress Classification System is at: http://lcweb.loc.gov/catdir/cpso/lcco/lcco.html
http://lcweb.loc.gov/catdir/cpso/lcco/lcco.html
More info at:http://lcweb.loc.gov/loc/legacy/loc.html
http://lcweb.loc.gov/loc/legacy/loc.html
The way the Dewey Decimal Classification and Relative Index was devised was by taking a snapshot of the courses taught at a random university (Melvil Dewey's Amherst College)
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